利用CAShapeLayer能够制作出随意的几何图形，把它作为UIImageView的遮罩，达到把图片做成圆形效果。

 imgView =  [[UIImageView alloc]initWithFrame:CGRectMake(10, 35, 80, 80)];
    imgView.image = [UIImage imageNamed:@"ma.jpg"];
    UIBezierPath* path = [UIBezierPath bezierPathWithArcCenter:CGPointMake(40, 40) radius:40 startAngle:0 endAngle:2*M_PI clockwise:YES];
    CAShapeLayer* shape = [CAShapeLayer layer];
    shape.path = path.CGPath;
    imgView.layer.mask = shape;
    [self.view addSubview:imgView];

以下在补充一个方法：

[m_photo.layer setCornerRadius:CGRectGetHeight([m_photo bounds]) / 2];//设置圆形半径
    m_photo.layer.masksToBounds = YES;
    m_photo.layer.borderWidth = 1;//设置外环宽度
    m_photo.layer.borderColor = [[UIColor greenColor] CGColor];//设置外环颜色
    m_photo.layer.contents = (id)[[UIImage imageNamed:@"index.png"] CGImage];//设置图片